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Date Published: 14/03/2024
Online Published: 14/03/2024
Abstract Views: 43
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DOI: https://doi.org/10.52714/dthu.13.2.2024.1236
Issue
Vol. 13 No. 2 (2024): Natural Sciences Issue (Vietnamese)
Section
Natural Sciences Issue
How to Cite
Pham, D. D. (2024). Removing Rhodamine B from aqueous solutions by Zn/Fe-doped MIL-53(Al). Dong Thap University Journal of Science, 13(2), 74-82. https://doi.org/10.52714/dthu.13.2.2024.1236

Removing Rhodamine B from aqueous solutions by Zn/Fe-doped MIL-53(Al)

Dinh Du Pham1,
1 Institute of Applied Technology, Thu Dau Mot University, Vietnam

Main Article Content

Abstract

In this paper, Zn/Fe-doped MIL-53(Al) and MIL-53(Al) were synthesized by solvothermal method in N’N-dimethylformamide. The material was characterized using XRD, FT-IR, TG, EDX, SEM, and nitrogen adsorption/desorption isotherms. This material’s catalytic adsorption was evaluated via its removal efficiency of rhodamine B (RB) from aqueous solution. The results show that doping with Zn is not favorable for the MIL-53 structure formed, while the material structure is almost unaffected when doping with Fe. But, MIL-53(Al, Fe) has higher adsorption capacity and catalytic activity than the other material samples. It shows that RB was completely removed after 240 minutes of the reaction on MIL-53(Al, Fe) catalyst at 60 °C (10 mg/L RB, 1.0 g/L of the catalyst, 0.192 M H2O2, pH 7). The decomposition reaction of RB by H2O2 on MIL-53(Al, Fe) occurs in a heterogeneous Fenton-like process.

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This work is licensed under a Creative Commons Attribution-NonCommercial 4.0 International License.

Keywords

Adsorption, heterogeneous Fenton, Rhodamine B, Zn/Fe-doped MIL-53(Al)

References

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