Study on the methylene blue treatment of hollow mesoporous silica nanoparticle synthesized from rice ash
Main Article Content
Abstract
HMSN materials were synthesized using the rice husk. The characteristic of the obtained samples was performed with X ray diffraction (XRD), IR, SEM , TEM and nitrogen adsorption (BET). The analysis results indicated that HMSN had hollow spherical shape structures with the surface area of 72.4963 m²/g, pore volume of 0.104 cm³/g and pore size of 8.6771 nm. XRD shows the presence and amorphous nature of silica. The obtained HMSNs exhibited good ability to adsorb methylene blue, the maximum adsorption capacity reached 30.2146 mg/g.
Article Details
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Keywords
HMSN, ash, methylenr blue, and molecular sieve
References
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[4] Y. Li, J. Shi, Hollow‐structured mesoporous materials: chemical synthesis, functionalization and applications, Advanced Materials, 26 (2014) 3176-3205.
[5] Y. Kuwahara, H. Kango, H. Yamashita, Pd nanoparticles and aminopolymers confined in hollow silica spheres as efficient and reusable heterogeneous catalysts for semihydrogenation of alkynesACS Catalysis 9 (2019) 1993.
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[7] S.S. Kim, W.Z. Zhang, T.J. Pinnavaia, Ultrastable Mesostructured Silica Vesicles, Science 282 (1998) 1302.
[8] D.B. Zhang, L.M. Qi, J.M. Ma, H.M. Cheng, Synthesis of Submicrometer-Sized Hollow Silver Spheres in Mixed Polymer–Surfactant Solutions, Adv Mater 14 (2002) 1499.
[9] Khanh B. Vu, Thanh Khoa Phung, Thao T.T. Tran et al., Polystyrene nanoparticles prepared by nanoprecipitation: A recyclable template for fabricating hollow silica, Journal of Industrial and Engineering Chemistry, 97 (2021) 307–315.
[10] Ngoc Tram Nguyen Thi, Linh Phuong Pham Tran, et al., The Engineering of Porous Silica and Hollow Silica Nanoparticles to Enhance Drug-loading Capacity, Processes, Vol 7(11), 2019.
[11] M.M. Titirici, M. Antonietti, A. Thomas, A generalized synthesis of metal oxide hollow spheres using a hydrothermal approach, Chem Mater 18 (2006) 3808.
[12] Y. Chen, H.-R. Chen, J.-L. Shi, Construction of homogenous/heterogeneous hollow mesoporous silica nanostructures by silica-etching chemistry: principles, synthesis, and applications, Accounts of chemical research, 47 (2014) 125-137.
[13] X. Fang, C. Chen, Z. Liu, P. Liu, N. Zheng, A cationic surfactant assisted selective etching strategy to hollow mesoporous silica spheres, Nanoscale, 3 (2011) 1632-1639.
[14] Y. Chen, H. Chen, L. Guo, Q. He, F. Chen, J. Zhou, J. Feng, J. Shi, Hollow/rattle type mesoporous nanostructures by a structural difference-based selective etching strategy, ACS nano, 4 (2010) 529-539.
[15] QN Khanh Nguyen, NT Yen, ND Hau, HL Tran, Synthesis and Characterization of Mesoporous Silica SBA-15 and ZnO/SBA-15 Photocatalytic Materials from the Ash of Brickyards, Journal of Chemistry 2020, ISSN 2090-9071(Online).
[16] Nguyễn Văn Hưng, Nguyễn Ngọc Bích, et al., Điều chế vật liệu nano SiO2 cấu trúc xốp từ tro trấu để hấp phụ xanh metylen trong nước, Tạp chí hóa học, 53(2015-4) 491-496.
[17] Nguyễn Trí Tuấn, Nguyễn Hữu Minh Phú, et al., Tổng hợp hạt nano SiO2 từ tro vỏ trấu bằng phương pháp kết tủa, Tạp chí Khoa học Trường Đại học Cần Thơ, 32 (2014): 120-124.
[18] Trần Nguyễn Phương Lan, Lương Huỳnh Vủ Thanh, Trần Thanh Trúc, et al., Tổng hợp zeolite NaA/NaX từ tro trấu không nung bằng phương pháp thủy nhiệt, Tạp chí Khoa học Trường Đại học Cần Thơ, Tập 56, Số 6A (2020), 22-32.