Enhanced durability of Mn-supported Fe/diatomite catalyst for phenol oxidation
Main Article Content
Abstract
In this paper, the Fenton-type oxidation of phenol over Mn-Fe/diatomite catalyst was studied. The Mn-Fe/diatomite composite was synthesised by using a hydrothermal process from a colloidal solution containing Mn(II), Fe(III), and diatomite. Under suitable synthesis conditions, the obtained Mn-Fe/diatomite contained 6.23% Fe and 0.10% Mn (by mass) with a specific surface area of 53.2 m2/g. Phenol conversion can reach 99% after 240 minutes of reaction on the Mn-Fe/diatomite catalyst (under the following conditions: phenol concentration 1 g/L; catalyst content 1 g/L; H2O2 content 6.5 g/L; reaction temperature 50°C). The bimetallic Mn-Fe/diatomite catalyst has lower oxidation activity than the monometallic Fe/diatomite catalyst but higher durability and reusability.
Keywords
Durability, Fenton-type, Mn-Fe/diatomite, phenol oxidation, reusability.
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