Investigating the adsorption of methylene blue from water by MnFe2O4/bentonite
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Abstract
The MnFe2O4/bentonite was obtained by wet chemical methods and was characterized by X-ray diffraction and N2-adsorption/desorption isotherms. Some factors affecting the MB adsorption process of materials such as pH, initial concentration, adsorbent mass, contact time and temperature were investigated. The results showed that dye adsorption capacity increased by increasing concentration, contact time, initial pH, and temperature. The adsorption kinetics of MB on modulation materials is consistent with the pseudo-second-order kinetics model. The adsorption isotherms well followed the Langmuir isotherm model and maximal adsorption capacity of methylene blue can read 119.05 mg/g at 323K. The adsorption behavior of MnFe2O4/bentonite is an endothermic and spontaneous process. The results show MnFe2O4/bentonite is a promising adsorbent for efficient removal of dye from wastewater.
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References
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Pang, J., Fu, F., Li, W., Zhu, L., & Tang, B. (2019). Fe-Mn binary oxide decorated diatomite for rapid decolorization of methylene blue with H2O2. Applied Surface Science, 478, 54-61.
Peng, H. H., Chen, J., Jiang, D. Y., Li, M., Feng, L., Losic, D., Dong, F., & Zhang, Y. X. (2016). Synergistic effect of manganese dioxide and diatomite for fast decolorization and high removal capacity of methyl orange. Journal of Colloid and Interface Science, 484, 1-9.
Peter, U. C., & Chinedu, U. (2016). Model prediction for constant area, variable pressure drop in orifice plate characteristics in flow system. Chem. Int, 2(8), 80-88.
Rahmani, A., Karimi, G. R., Rahmani, A., Hosseini, M., & Rahmani, A. (2017). Removal/separation of Co(II) ion from environmental sample solutions by MnFe2O4/bentonite nanocomposite as a magnetic nanomaterial, Desalin. Water Treat, 89, 250-257.
Sun, Z., Yao, G., Liu, M., & Zheng, S. (2017). In situ synthesis of magnetic MnFe2O4/diatomite nanocomposite adsorbent and its efficient removal of cationic dyes. Journal of the Taiwan Institute of Chemical Engineers, 71, 501-509.
Taher, T., Mohadi, R., Rohendi, D., & Lesbani, A., Kinetic and thermodynamic adsorption studies of congo red on bentonite. in AIP Conference Proceedings, 2017: AIP Publishing LLC.
Taher, T., Rohendi, D., Mohadi, R., & Lesbani, A. (2018). Thermal and Acid Activation (TAA) of bentonite as adsorbent for removal of methylene blue: A kinetics and thermodynamic study. Chiang Mai Journal of Science, 45(4), 1770-1781.
Tan, I., Ahmad, A., & Hameed, B. (2008). Adsorption of basic dye on high-surface-area activated carbon prepared from coconut husk: Equilibrium, kinetic and thermodynamic studies. Journal of hazardous materials, 154(1-3), 337-346.
Visa, M., Andronic, L., Lucaci, D., & Duta, A. (2011). Concurrent dyes adsorption and photo-degradation on fly ash based substrates. Adsorption, 17(1), 101-108.
Zhang, H., Zhou, J., Muhammad, Y., Tang, R., Liu, K., Zhu, Y., & Tong, Z. (2019). Citric acid modified bentonite for Congo Red adsorption. Frontiers in Materials, 6, 5.
Zhao, Y., Li, Q., Ren, H., & Zhou, R. (2017). Activation of persulfate by magnetic MnFe2O4-bentonite for catalytic degradation of 2, 4-dichlorophenol in aqueous solutions. Chemical Research in Chinese Universities, 33(3), 415-421.
Belachew, N., & Bekele, G. (2020). Synergy of magnetite intercalated bentonite for enhanced adsorption of congo red dye. Silicon, 12(3), 603-612.
Bellifa, A., Makhlouf, M., & Boumila, Z. H. (2017). Comparative study of the adsorption of methyl orange by bentonite and activated carbon. Acta Phys. Pol. A, 132, 466-468.
Bulut, Y., & Aydin, H. (2006). A kinetics and thermodynamics study of methylene blue adsorption on wheat shells. Desalination, 194(1-3), 259-267.
Dang, T.-D., Banerjee, A. N., Tran, Q.-T., & Roy, S. (2016). Fast degradation of dyes in water using manganese-oxide-coated diatomite for environmental remediation. Journal of Physics and Chemistry of Solids, 98, 50-58.
Hashem, F. (2012). Adsorption of methylene blue from aqueous solutions using Fe3O4/bentonite nanocomposite. Hydrology: Current Research, 3(5), 1-6.
Hassani, A., Khataee, A., Karaca, S., Karaca, M., & Kıranşan, M. (2015). Adsorption of two cationic textile dyes from water with modified nanoclay: a comparative study by using central composite design. Journal of Environmental Chemical Engineering, 3(4), 2738-2749.
Janoš, P., Buchtova, H., & Rýznarová, M. (2003). Sorption of dyes from aqueous solutions onto fly ash. Water research, 37(20), 4938-4944.
Kanwal, A., Bhatti, H. N., Iqbal, M., & Noreen, S. (2017). Basic dye adsorption onto clay/MnFe2O4 composite: a mechanistic study. Water Environment Research, 89(4): 301-311.
Madan, S., Shaw, R., Tiwari, S., & Tiwari, S. K. (2019). Adsorption dynamics of Congo red dye removal using ZnO functionalized high silica zeolitic particles. Applied Surface Science, 487, 907-917.
Mahmoudian, M., Balkanloo, P. G., & Nozad, E. (2018). A facile method for dye and heavy metal elimination by pH sensitive acid activated montmorillonite/polyethersulfone nanocomposite membrane. Chinese Journal of Polymer Science, 36(1), 49-57.
Nguyen, L. M. L., Duong, T., Van Duc, H., Thi Anh Thu, N., Khac Lieu, P., Van Hung, N., Hoa, L. T., & Quang Khieu, D. (2020). Phenol red adsorption from aqueous solution on the modified bentonite. Journal of Chemistry, 2020, 1-14.
Niu, S., Xie, X., Wang, Z., Zheng, L., Gao, F., & Miao, Y. (2021). Enhanced removal performance for Congo red by coal-series kaolin with acid treatment. Environmental technology, 42(10), 1472-1481.
Pang, J., Fu, F., Li, W., Zhu, L., & Tang, B. (2019). Fe-Mn binary oxide decorated diatomite for rapid decolorization of methylene blue with H2O2. Applied Surface Science, 478, 54-61.
Peng, H. H., Chen, J., Jiang, D. Y., Li, M., Feng, L., Losic, D., Dong, F., & Zhang, Y. X. (2016). Synergistic effect of manganese dioxide and diatomite for fast decolorization and high removal capacity of methyl orange. Journal of Colloid and Interface Science, 484, 1-9.
Peter, U. C., & Chinedu, U. (2016). Model prediction for constant area, variable pressure drop in orifice plate characteristics in flow system. Chem. Int, 2(8), 80-88.
Rahmani, A., Karimi, G. R., Rahmani, A., Hosseini, M., & Rahmani, A. (2017). Removal/separation of Co(II) ion from environmental sample solutions by MnFe2O4/bentonite nanocomposite as a magnetic nanomaterial, Desalin. Water Treat, 89, 250-257.
Sun, Z., Yao, G., Liu, M., & Zheng, S. (2017). In situ synthesis of magnetic MnFe2O4/diatomite nanocomposite adsorbent and its efficient removal of cationic dyes. Journal of the Taiwan Institute of Chemical Engineers, 71, 501-509.
Taher, T., Mohadi, R., Rohendi, D., & Lesbani, A., Kinetic and thermodynamic adsorption studies of congo red on bentonite. in AIP Conference Proceedings, 2017: AIP Publishing LLC.
Taher, T., Rohendi, D., Mohadi, R., & Lesbani, A. (2018). Thermal and Acid Activation (TAA) of bentonite as adsorbent for removal of methylene blue: A kinetics and thermodynamic study. Chiang Mai Journal of Science, 45(4), 1770-1781.
Tan, I., Ahmad, A., & Hameed, B. (2008). Adsorption of basic dye on high-surface-area activated carbon prepared from coconut husk: Equilibrium, kinetic and thermodynamic studies. Journal of hazardous materials, 154(1-3), 337-346.
Visa, M., Andronic, L., Lucaci, D., & Duta, A. (2011). Concurrent dyes adsorption and photo-degradation on fly ash based substrates. Adsorption, 17(1), 101-108.
Zhang, H., Zhou, J., Muhammad, Y., Tang, R., Liu, K., Zhu, Y., & Tong, Z. (2019). Citric acid modified bentonite for Congo Red adsorption. Frontiers in Materials, 6, 5.
Zhao, Y., Li, Q., Ren, H., & Zhou, R. (2017). Activation of persulfate by magnetic MnFe2O4-bentonite for catalytic degradation of 2, 4-dichlorophenol in aqueous solutions. Chemical Research in Chinese Universities, 33(3), 415-421.
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